By Peter Harriott
Analyzes rules and methods for the review, evaluation, and optimization of reactors within the production, chemical, petrochemical, and foodstuff processing industries. Illustrates functional layout techniques, cost equations, and analytical types for superior reactor functionality.
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C. 37 have been better to determine the time for a constant percent decomposition—say, 50%—at different temperatures? 9. What is the order with respect to sulfuric acid? 2 The thermal decomposition of plutonium hexaﬂuoride was studied in a batch reactor made of nickel . The reactor was pretreated with ﬂuorine before use: PuF6ðgÞ ! 10 were reported for a reaction time of 90 min at 161 C. a. b. c. Assume concurrent zero-order and ﬁrst-order reactions (as the authors did), integrate the rate equation, and determine the best values of the rate constants.
Oxidation of Nitrogen in Combustion. M. ). Academics of Sciences of the USSR. Moscow: Institute of Chemical Physics, 1947. 5. F Rodriguez. Polymer 23:1473, 1982. 6. L Michaelis, ML Menton. Biochem Z 48:333, 1913. 7. ML Shuler, F Kargi. Bioprocess Engineering. Englewood Cliffs, NJ: PrenticeHall, 1992. 8. KM Plowman. Enzyme Kinetics. New York: McGraw-Hill, 1972. 9. JH Seinfeld. Air Pollution: Physical and Chemical Fundamentals. New York: McGraw-Hill, 1975. 10. GF Froment, KB Bischoff. Chemical Reactor Analyses and Design.
What is the signiﬁcance of the different orders? 12) . How well can the decrease in rate constant be accounted for using the simple activation theory of Lindemann? Determine this value of k1 , and compare with the author’s value of 8:88 Â 10À3 secÀ1 . C2 H5 Cl ! 5 The thermal reaction H2 þ Br2 ! 2HBr is thought to proceed by the chain mechanism given here, with appropriate rate constants at 800 K. 114 g M ¼ monomer concentration. 07 1 M þ Br2 À! 2Br þ M 2 Br þ H2 À! HBr þ H 3 H þ Br2 À! HBr þ Br 4 H þ HBr À!